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Synthesis of 1,2,3-triazines

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Readily accessible (Z)-4-aryl-2,4-diazido-2-alkenoates can efficiently be converted to 6-aryl-1,2,3-triazine-4-carboxylate esters under mildly basic conditions without the assistance of any transition metals or strong acid.
H. Sugimura, R. Takeuichi, S. Ichikawa, E. Nagayama, I. Sasaki, Org. Lett., 2018, 20, 3434-3437.