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Synthesis of tetrahydroquinoxalines

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SN2-type ring-opening of activated aziridines with 2-bromoanilines followed by a Pd-catalyzed intramolecular C-N bond formation enable a highly regio- and stereoselective route for the synthesis of racemic and nonracemic tetrahydroquinoxalines.
M. K. Ghorai, A. K. Sahoo, S. Kumar, Org. Lett., 2011, 13, 5972-5975.